Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra
Lerma-Berlanga, Belen; Castells-Gil, Javier; Ganivet, Carolina R.; Almora-Barrios, Neyvis; Gonzalez-Platas, Javier; Fabelo, Oscar; Padial, Natalia M.; Marti-Gastaldo, Carlos
Publicación: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2021
VL / 143 - BP / - EP /
abstract
Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m(2).g(-1).
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